Seasonal characteristics of aerosol optical properties in Sky Radiometer Network (SKYNET) Hefei site are studied using a sky radiometer from March 2007 to May 2013. The aerosol optical depth (AOD), Angstrom exponent (AE), volume size distributions, single-scattering albedo (SSA), refractive index, and asymmetry factor (ASY) of aerosols are simultaneously retrieved using the SKYRAD.pack version 4.2 software. During the study period, the AOD varied seasonally, with the maximum value of 1.02 ± 0.42 at 500 nm occurring in the summer, and the highest AOD (1.13 ± 0.42) occurred in June due to stagnant climate conditions and accumulation of polluted aerosols before the East Asian summer monsoon. The variation in AE showed a different pattern, with the minimum (0.97 ± 0.28) and maximum values (1.30 ± 0.22) occurring during the spring and fall seasons, respectively. The relatively low value of AE in spring is related to the emission of Asian dust events. The aerosol volume size distributions can be expressed by the trimodal patterns for each season, consisting of a fine mode with R < 0.6 μm, a coarse mode with R > 2.5 μm, and a middle mode located between them. The real part of the refractive index increased with wavelength (380-870 nm) while the imaginary part of the refractive index decreased for all seasons except for the summer. The seasonal mean values of SSA were 0.97 ± 0.02 (summer), 0.95 ± 0.03 (spring), 0.93 ± 0.04 (autumn), and 0.91 ± 0.04 (winter) at 380 nm indicating more absorbing aerosol in the autumn and winter months. Furthermore, aerosol properties were greatly modified by condensation growth as evidenced by the positive dependencies of AOD, SSA, and ASY on relative humidity.
IntroductionAerosols alter the radiative balance of the Earth atmosphere system by scattering and absorbing shortwave and longwave radiation directly [Charlson et al., 1992]. Indirectly, aerosols can modify cloud microphysical properties and hence the radiative properties, amount, and lifetime of clouds, which will affect the climate [IPCC, 2007;Ramanathan et al., 2008]. Despite a substantial increase in the efforts to further understand aerosols and their climatic effects [Dubovik et al., 2002;Nakajima et al., 2003;Ramanathan et al., 2005;Li et al., 2007aLi et al., , 2011Xia et al., 2007aXia et al., , 2007bXin et al., 2007;Lee et al., 2007;Che et al., 2009a], considerable uncertainties still exist due to the large spatial and temporal variations of aerosol amount and properties and strong interactions of aerosols with other atmospheric processes [IPCC, 2001[IPCC, , 2007. Therefore, it is necessary to quantitatively characterize the aerosol optical properties (AOP) in different regions of climatic significance, especially in eastern China, where high aerosol loading is common and can thus impact areas downwind through long-range transportation. This is evident from the global aerosol optical depth (AOD) distribution from Moderate Resolution Imaging Spectroradiometer (MODIS) Kim et al., 2007].Both in situ and remote sensin...