We present ground-based limb polarization measurements of Jupiter and Saturn consisting of full disk imaging polarimetry for the wavelength 7300Å and spatially resolved (long slit) spectropolarimetry covering the wavelength range 5200 to 9350Å.For the polar region of Jupiter we find for λ = 6000Å a very strong radial (perpendicular to the limb) fractional polarization with a seeing corrected maximum of about +11.5 % in the South and +10.0 % in the North. This indicates that the polarizing haze layer is thicker at the South pole. The polar haze layers extend down to 58• in latitude. The derived polarization values are much higher than reported in previous studies because of the better spatial resolution of our data and an appropriate consideration of the atmospheric seeing. Model calculations demonstrate that the high limb polarization can be explained by strongly polarizing (p ≈ 1.0), high albedo (ω ≈ 0.98) haze particles with a scattering asymmetry parameter of g ≈ 0.6 as expected for aggregate particles of the type described by West and Smith (1991). The deduced particle parameters are distinctively different when compared to lower latitude regions.The spectropolarimetry of Jupiter shows a decrease in the polar limb polarization towards longer wavelengths and a significantly enhanced polarization in strong methane bands when compared to the adjacent continuum. This is a natural outcome for a highly polarizing haze layer above an atmosphere where multiple scatterings are suppressed in absorption bands. For lower latitudes the fractional polarization is small, negative, and it depends only little on wavelength except for the strong CH 4 -band at 8870Å.The South pole of Saturn shows a lower polarization (p ≈ 1.0 − 1.5 %) than the poles of Jupiter. The spectropolarimetric signal for Saturn decrease rapidly with wavelength and shows no significant enhancements in the fractional polarization in the absorption bands. These properties can be explained by a vertically extended stratospheric haze region composed of small particles < 100 nm as suggested previously by Karkoschka and Tomasko (2005).In addition we find in the V-and R-band a previously not observed strong polarization feature (p = 1.5 − 2.0 %) near the equator of Saturn. The origin of this polarization signal is unclear but it could be related to a seasonal effect.Finally we discuss the potential of ground-based limb polarization measurements for the investigation of the scattering particles in the atmospheres of Jupiter and Saturn.