Chemical and electrochemical syntheses of the binuclear zinc and cadmium chelates based on the sterically hindered Schiff bases

Cadmium and tin complexes of Schiff-base ligands

“…Electrochemical dissolution of zero valent Cd in methanol, in the presence of equimolar amounts of ligand, made it possible to isolate dimeric complexes[52]. Diamagnetic [Cd(SB1) 2 (acphen)] (10) and [Cd(SB2) 2 (acphen)](11), shown in figure 7[53], have been prepared from Cd(II) with monobasic neutral Schiff bases bis-(acetophenone)ethylenediamine (figure 8), 5-chlorosalicylideneaniline, or 5-bromosalicylideneaniline (figure 9) (yellow).…”

Zinc Schiff Base Complexes Derived from 2,2'‐Diaminobiphenyls: Solution Behavior and Reactivity towards Nitrogen Bases

“…The value is comparable with what has previously been reported for Schiff base complexes of Cd. [42c], Cd satellites were also observed in the 13 C NMR spectrum of the complex, but only three‐bond coupling constants could be detected, and only for carbons in the phenoxide rings of the complex. 3 J C,Cd values for C 10 and C 8 were found to be 15.0 Hz and 21.0 Hz, respectively (Figure ).…”

Synthesis, Characterization, and Crystal Structure of a Dinuclear Cadmium(II) Complex Derived From 4-Chloro-2-{[2-(2-Hydroxyethylamino)Ethylimino]Methyl}Phenol

“…[2,3] Cadmium complexes with Schiff bases derived from salicylaldehyde and its derivatives have been received much attention in coordination chemistry due to their interesting structures and properties. [4][5][6][7][8] A number of the dinuclear cadmium(II) complexes were prepared with the macrocyclic Schiff bases. [9][10][11][12][13] However, those with the asymmetric tri-or tetradentate Schiff bases are relatively rare.…”