Chemical modification of polysulfone: anionic synthesis of dipyridyl functionalized polysulfone

Summers, Gabriel J.; Ndawuni, Mzikayise Patrick; Summers, Carol A.

doi:10.1016/s0032-3861(00)00345-1

Cited by 19 publications

(6 citation statements)

References 21 publications

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“…Regardless of the preparation method, the subsequent reactions of the lithiated polysulfones give the possibility to introduce quantitatively many functional groups such as carboxylate, alcohol, azide, primary amine, tertiary amine, benzamine, aldehyde, dipyridyl, trimethylsilyl, phosphonic acid and sulfonate from commercially available electrophiles (Scheme ). These functional polysulfones can further facilitate various applications.…”

Section: Chemical Functionalizationmentioning

confidence: 99%

Recent advances in the preparation of functionalized polysulfones

Dizman

Taşdelen

Yaǧcı

2013

Polymer International

126

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Section: Chemical Functionalizationmentioning

confidence: 99%

Recent advances in the preparation of functionalized polysulfones

Dizman

Taşdelen

Yaǧcı

2013

Polymer International

126

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“…Transparent, rigid and high-strength polymers, they exhibit excellent impact resistance over a wide temperature range and are highly resistant to water, steam, acids and oxidizing agents [19]. Their structure is formed by a monomeric unit which contains phenyl, ether and sulfone moieties.…”

Section: Introductionmentioning

confidence: 99%

High performance PEEK/carbon nanotube composites compatibilized with polysulfones-I. Structure and thermal properties

Díez‐Pascual

Naffakh

González‐Domínguez

et al. 2010

Carbon

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“…In certain harsh circumstances, high-performance engineering plastics are needed to meet the application requirement [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 ]. Polyarylene ether nitrile (PEN) is a kind of polyaryl ether polymer with the cyano group in its side group.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Properties of Semicrystalline Poly(ether nitrile ketone) Copolymers

Zhu,

Mo,

Tong

et al. 2024

Polymers

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As a high-performance engineering plastic, polyarylene ether nitrile (PEN) is widely used in many fields. The presence of cyano groups of PEN ensures its good adhesion to other substrates, but the inherent low crystallinity of PEN limits its application. In this work, the poly(aryl ether ketone) segment was introduced into PEN via copolymerization using both 2,6-Dichlorobenzonitrile and 4,4′-Difluorobenzophenone as the starting reagents to prepare poly (ether nitrile ketone) (BP-PENK). The effect of composition and thermal treatment on the crystallization behavior and properties of poly (ether nitrile ketone) were systematically studied. It was found that when the content of DFBP is 30%, the copolymer BP-PENK30 had the best mechanical properties, with a tensile strength of 109.9 MPa and an elongation at a break value of 45.2%. After thermal treatment at 280 °C for 3 h, BP-PENK30 had the highest crystallinity with a melting point of 306.71 °C, a melting enthalpy of 5.02 J/g, and crystallinity of 11.83%. Moreover, with the increase in crystallinity, the dielectric constant and energy density increased after thermal treatment. Therefore, the introduction of poly(aryl ether ketone) chain segments and thermal treatment can effectively improve the crystallization and the comprehensive properties of PEN.

show abstract

Chemical modification of polysulfone: anionic synthesis of dipyridyl functionalized polysulfone

Cited by 19 publications

References 21 publications

Recent advances in the preparation of functionalized polysulfones

Recent advances in the preparation of functionalized polysulfones

High performance PEEK/carbon nanotube composites compatibilized with polysulfones-I. Structure and thermal properties

Synthesis and Properties of Semicrystalline Poly(ether nitrile ketone) Copolymers

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