Chemiluminescence during the oxidation of alcohols by permanganate: Application to the determination of ethanol in gin

Montalvo, S.I.; Ingle, J. D.

doi:10.1016/0039-9140(93)80317-k

Cited by 18 publications

(8 citation statements)

References 7 publications

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“…Ferrous ions (Mohr's salt) were added to the sample and carrier water, because addition of ferrous ion enhances CL emissions. 6,8 The concentration of ferrous ion was 10 µmol/l (10 mmol/l H2SO4) for the sample and carrier water. Ten mmol/l pyrogallol in artificial seawater with a salinity of 3.4% was used as a standard solution.…”

Section: Apparatus and Analytical Methodsmentioning

confidence: 99%

Chemiluminescence Method with Potassium Permanganate for the Determination of Organic Pollutants in Seawater

Fujimori

Moriuchi‐Kawakami

et al. 2001

ANAL. SCI.

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Section: Apparatus and Analytical Methodsmentioning

confidence: 99%

Chemiluminescence Method with Potassium Permanganate for the Determination of Organic Pollutants in Seawater

Fujimori

Moriuchi‐Kawakami

et al. 2001

ANAL. SCI.

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“…Over the years, research had been done to study the effect of H 2 SO 4 concentration on the COD Mn test [10,12]. In addition, the effects of the digestion period and the digestion temperature on the COD OH test were also studied.…”

Section: Optimum Conditions For Cod Mn and Cod Oh Testsmentioning

confidence: 99%

Potassium Permanganate as Oxidant in the Cod Test for Saline Water Samples

Goh

Lim

2017

AJSTD

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The objective of this study is to investigate the feasibility of applying potassium permanganate (KMnO 4 ) as the oxidant in the COD test for highly saline water samples. Initially, the COD values of various glucose standard solutions were determined by three methods, namely the standard closed reflux dichromate (COD Cr ), the acidic permanganate (COD Mn ) and the alkaline permanganate (COD OH ) methods. The results showed that at COD values lower than 20 mg/L, the standard dichromate method was not applicable due to its poor precision (RSD > 10%). The COD OH method was less effective compared to the COD Mn method as the recoveries were 0.71 and 0.89, respectively. The determination of COD OH for the standard solutions of glucose in the presence of Cl -and Br -, respectively, or both Cl -and Br -ions were conducted. The results showed that the COD values only increased 5.1% with the increase in chloride concentrations up to 35000 mg Cl -/L. This shows that the COD OH method is a suitable method for determining the COD of highly saline water samples such as estuarine and coastal waters. The COD test was conducted for river, estuarine and coastal water samples. The results indicated that the COD OH test correlates well with the COD Cr test (R 2 > 0.98). The results also indicated that this COD OH test can be applied in determining the pollution trends for estuarine and coastal waters.

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“…Potassium permanganate discovered by Margueritte in 1846 has now been widely used for redox reactions involving a variety of chemical reactions. It is a versatile strong oxidizing agent in both acidic and alkaline media which has been employed for the oxidation of various organic compounds like alcohols [1][2][3], aldehydes and ketones [4][5][6], amines [7], glyoxal and glyoxalic acid [8].…”

Section: Introductionmentioning

confidence: 99%

Kinetics and Mechanism of Propane-1,3-diol Oxidation by Mn(VII) in Aqueous Medium

Latona

2019

Adv. J. Chem. A

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The oxidation of propane-1, 3-diol by potassium permanganate in aqueous solution was investigated at λmax 525 nm. The rate of the reaction was found to increase with increase in [KMnO4] and [Propane-1, 3-diol]. The reaction showed first order dependence each in [KMnO4] and [Propane-1, 3-diol] and independent in the ionic strength of the solution. The values of ∆ # (kJ mol -1 ), ∆ # (kJK -1 mol -1 ) ∆ # (kJ mol -1 ) were 24.98, -0.22 and 90.50 respectively. Negative activation of entropy revealed an ordered transition state for the reaction. Spectroscopic studies and FTIR analysis revealed the product of the reaction to be 3-hydroxy-propanone.

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Chemiluminescence during the oxidation of alcohols by permanganate: Application to the determination of ethanol in gin

Cited by 18 publications

References 7 publications

Chemiluminescence Method with Potassium Permanganate for the Determination of Organic Pollutants in Seawater

Chemiluminescence Method with Potassium Permanganate for the Determination of Organic Pollutants in Seawater

Potassium Permanganate as Oxidant in the Cod Test for Saline Water Samples

Kinetics and Mechanism of Propane-1,3-diol Oxidation by Mn(VII) in Aqueous Medium

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