Chemiluminescence of organic hydrazides

The emitting species formed by the oxidation of hydrazides with hypohalites or N‐halosuccinimides

“…This is in agreement with previous evidence for open-chain hydrazides (3,4). In contrast to Tsaplev's evidence for an aldehyde emitter, the same spectral distribution was observed from the oxidation of this hydrazide with either hypochlorite or hypobromite (Fig.…”

“…The pathway to this emitter is dependent on the nature of the oxidizing species and the presence or absence of hydrogen peroxide (2). It is generally accepted that oxidations of other hydrazides occur through analogous reaction pathways, although most studies have focused on oxidation by oxygen in dimethyl sulphoxide or by hydrogen peroxide in water in the presence of a base (3,4).…”

Chemiluminescence of 5-(azo-para-phenylene-N-aza-15-crown-5)-phthalhydrazide

“…[1][2][3][4][5][6][7] In alkaline medium, in the presence of oxygen, [2][3][4]8 hydrogen peroxide, and transitional metal ions such as Fe 3+ , its CL intensity (I CL ) is enhanced. [9][10][11] Based on its CL, luminol is being used for the bioanalytical determination of enzymatically-formed oxidizing species such as the superoxide anion and the hydroxyl radical.…”

Chemiluminescence of 4‐styrylphthal‐hydrazides with crown ether as ionophore

“…The chemiluminescence of phthalhydrazides is based on their oxidation reactions that form fluorescent phthalate dianions in the excited states (1). Of a number of various phthalhydrazides, luminol (2-aminophthalhydrazide) is the most popular and frequently used as a chemiluminescent compound, whose noticeable feature is to act as an analytical tools by emitting light as the signal indicating the presence as well as the amount of widespread target substances such as blood for a criminal investigation (2).…”