ChemInform Abstract: ACETYLCHOLINESTERASE‐REAKTIVATOREN, PYRIDYL‐ UND ANILYL‐TRIFLUORMETHYLKETOXIME

Salvador, R. L.; Saucier, Michel; Simon, David Z.; Goyer, Robert A.

doi:10.1002/chin.197238264

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2018

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“…Quinoline oxime ligands were prepared from quinoline aldehydes (Schemes 1−3). 11 Scheme 1 depicts the synthesis of ligand 4 and its corresponding Re(I) complex (Re4im). Addition of TMS-CF 3 to quinoline-8-carbaldehyde, catalyzed by K 2 CO 3 , affords the TMS-protected alcohol 1, and cleavage of the TMS protecting group with TBAF yields alcohol 2.…”

Section: ■ Introductionmentioning

confidence: 99%

Structure, Spectroscopy, and Electrochemistry of Manganese(I) and Rhenium(I) Quinoline Oximes

et al. 2018

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Reactions of α- and β-diimine quinoline aldoximes with Mn(I) and Re(I) tricarbonyl halides afford quinoline oxime complexes. Both Mn(I) and Re(I) complexes experience severe geometric strain due to ligand steric interactions: 6-membered metallocycles exhibit more pronounced distortions than 5-membered ones, consistent with density functional theory structural analyses. Such distortions likely also affect reactivity patterns, as evidenced by Re(I)-induced deoximation of a quinoline variant containing a CF3-ketoxime.

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Section: ■ Introductionmentioning

confidence: 99%

Structure, Spectroscopy, and Electrochemistry of Manganese(I) and Rhenium(I) Quinoline Oximes

et al. 2018

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ChemInform Abstract: ACETYLCHOLINESTERASE‐REAKTIVATOREN, PYRIDYL‐ UND ANILYL‐TRIFLUORMETHYLKETOXIME

Abstract: Die Lithiumverbindungen (I) liefern bei der Umsetzung mit dem Trifluoracetamid (II) nach anschließender Hydrolyse die Ketone (III), aus denen durch Behandlung mit Hydroxylamin die Oxime (IV) erhalten werden.

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Structure, Spectroscopy, and Electrochemistry of Manganese(I) and Rhenium(I) Quinoline Oximes

Structure, Spectroscopy, and Electrochemistry of Manganese(I) and Rhenium(I) Quinoline Oximes

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