ChemInform Abstract: CHEMISTRY OF PHOSPHORUS. PART 141. SODIUM PHOSPHIDE (NA3P21) AND LITHIUM PHOSPHIDE (LI3P21), THE FIRST POLYPHOSPHIDES CONTAINING ISOLATED P213‐ STRUCTURAL GROUPS
Abstract:Während Na3P21 bei der Umsetzung von weißem Pmit Na in THF gebildet wird, entsteht Li3P21 (nicht isoliert) bei der Reaktion von Li3P7 mit Iod oder 1,2‐Dibromethan sowie bei der Metallierung von P7H3 mit Li‐dihydrogenphosphid oder n‐Butyllithium.
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