ChemInform Abstract: Chemistry of Phosphorus. Part 188. Halogen‐Substituted Cyclohexaphosphanes: Formation and Properties of (PCl)6 and (PBr)6.

Abstract

The title compounds (III) and (VI), prepared by partial dehalogenation of the corresponding phosphorus trihalides, are the first perhalogenated cyclophosphanes which are only stable in diluted solutions at low temperature.