Abstract:Die Titelverbindung (II) wird als 1/3‐Hydrat aus dem cis‐Sulfitocyanocobaltat (I) durch Eindampfen mit Königswasser, Abrauchen mit HCl, Auflösen des Produktes in konz. Ammoniak und Erhitzen im Autoklaven dargestellt (Raman‐, IR‐, Elektronenspektrum, Kristallstruktur).
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