Darstellung, Eigenschaften und Spektren von cis‐[Co(CN)3(NH3)3] werden beschrieben. Die Röntgenstrukturanalyse beweist die cis‐Konfiguration. Bei der thermischen Zersetzung entstehen Co2(CN)5NH2 und Co2(CN)5. Mit Ag+ und Hg2+ werden Überkomplexe gebildet.
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