ChemInform Abstract: Derivatives of the Phosphorous Acid o‐Phenyleneester. Part 39. Chlorination of a Cyclic Chloro‐dithiophosphite.

Abstract

1992 organo-phosphorus compounds, nonmetal heterocycles organo-phosphorus compounds, nonmetal heterocycles S 0087 -239Derivatives of the Phosphorous Acid o-Phenyleneester. Part 39. Chlorination of a Cyclic Chloro-dithiophosphite.-The reaction of (I) with chlorine is reinvestigated. NMR spectroscopic investigations reveal that PCl3 is obtained beside a polymeric disulfide. A corresponding dichlorophosphonium salt, as is demonstrated in the reaction of (I) with SbCl5, cannot be found. -(GLOEDE, J.; WASCHKE, R.; Phosphorus, Sulfur Silicon Relat.