ChemInform Abstract: Direct Formation of 2,5‐Dimethyl‐3,3a,4‐trithia‐1‐azapentalenium and 4,6‐Dimethyl‐3‐thioxo‐3H‐1,2‐dithiolo[4,3‐c]pyridinium from Acetonitrile and Hydrogen Sulfide. Crystal Structures of Their Compounds with (UBr₆)^2‐ and (UO₂Br₄)^2‐.

Abstract

The title compounds (IV) and (V) are formed, along with other products, by the reaction of H2S (II) with a MeCN (III) solution of UBrS (I).