ChemInform Abstract: Dirhodium(II)‐Catalyzed Intramolecular C—H Amination of Aryl Azides.

Abstract

Indole derivatives R 0140Dirhodium (II)-Catalyzed Intramolecular C-H Amination of Aryl Azides. -The reaction proceeds with generally high yields in the presence of a rhodium catalyst and molecular sieves. It is shown that (E)-and (Z)-isomers generate the same product [cf. (XII)] with comparable yield; however with different catalysts. -(SHEN, M.; LESLIE, B. E.; DRIVER*, T. G.; Angew.