ChemInform Abstract: Divergent Roles of Urea and Phosphoric Acid Derived Catalysts in Reactions of Diazo Compounds.

Bernardim, Barbara; Couch, Erica D.; Hardman‐Baldwin, Andrea M.; Burtoloso, Antonio C. B.; Mattson, Anita E.

doi:10.1002/chin.201629022

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Table 1 Optimization Of the S–h Insertion Reac...1

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2023

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“…4 To date, various strategies have emerged to realize this reaction. For example, transition-metal catalysis, 5 organocatalysis, 6 heterogeneous catalysis, 7 biocatalysis, 8 and photocatalysis 9 have proven useful in the context of this reaction (Scheme 1 ). Although they represent significant achievements, these procedures typically not only require elaborately selected catalysts but also diazo compounds.…”

Section: Table 1 Optimization Of the S–h Insertion Reac...mentioning

confidence: 99%

A New Approach to the S–H Insertion Reaction of α-Keto Esters and Thiols

Yuan¹,

Fang²,

Tian³

et al. 2023

Synlett

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Sulfur-containing compounds are well known for their frequent occurrence in a large number of natural and synthetic molecules with relevant biological activity. An easy and highly efficient approach to sulfur-containing compounds, by S–H insertion reactions of α-keto esters with thiols, is reported. The substrate scope was remarkably wide, affording the corresponding products in up to 97% yield. Overall, the raw materials were readily available and the reaction conditions were mild in this synthetic method.

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Section: Table 1 Optimization Of the S–h Insertion Reac...mentioning

confidence: 99%