ChemInform Abstract: EFFECT OF CARBON TETRACHLORIDE ON ALKYL PHOSPHINITES

Abstract

Bei der Umsetzung des Phosphinits (I) mit Tetrachlorkohlenstoff (II) entsteht ein präparativ nicht trennbares Gemisch aus zahlreichen Verbindungen, von denen spektroskopisch l die Substanzen (III)‐(VI) nachgewiesen wurden.

Formation of aryl dialkylphosphinates from dialkylphosphinous chlorides and arylmagnesium bromides under oxidative conditions

“…The 31 P NMR chemical shifts and the molecular weights obtained by electron impact-mass spectrometry (EI-MS) are also included. The compounds prepared (2a-d and 3a-d) are all new species; the analogous Et 2 P(O)Ph and Et 2 P(O)OPh derivatives were, however, described earlier [5,6]. For the former compound, a d P of 48.8 [5], and for the latter, a d P of 61.0 were reported [6], which seem to match our values ( Table 1).…”

“…The compounds prepared (2a-d and 3a-d) are all new species; the analogous Et 2 P(O)Ph and Et 2 P(O)OPh derivatives were, however, described earlier [5,6]. For the former compound, a d P of 48.8 [5], and for the latter, a d P of 61.0 were reported [6], which seem to match our values ( Table 1). The mass spectrum of the individual components were determined by gas chromatography-mass spectrometry (GC-MS) ( Table 2).…”