ChemInform Abstract: ELEMENTORGANISCHE DERIVATE DES ALPHA‐PHENYLAETHYLHYDROPEROXIDS

Abstract

Technisches α‐Phenyl‐äthylhydroperoxid (I) wird durch Überführung in das Natriumsalz und dessen Zersetzung mittels Kohlendioxid in wäßriger Phase gereinigt.

Synthetic and mechanistic studies of (p-p) pi-bonded organosilicon and organogermanium reactive intermediates

“…For the series Ph-Si-O-O-GPh (Me)-, the relative rates were 1:8:20 for n = 1-3. Ihe 3 n^ '3-n rate of reaction also depends on the nature of the alkyl groups around the silicon atom (92). For the series R^SiOOGH(Me)(Ph), the rates in crease in the order R = Me<Et<Pr.…”