ChemInform Abstract: GROUP EXCHANGE REACTIONS‐ METHYL EXCHANGE IN ACRYLIC ACID DERIVATIVES BY A MULTI‐STEP REACTION

Abstract

Acrylnitril und Acrylester (I) reagieren mit dem aus Trisdimethylamino‐methan und Eisenpentacarbonyl erhaltenen Salz (II) unter Annahme von Zwischenstufen wie (III) zu den Folgeprodukten (IV) und (V), wobei höhere Reaktionstemperaturen die Bildung von (V) begünstigen.

Synthesis of Deuterated Heterocycles with Me2NCD(OMe)2 and Evaluation of the Products for Metabolism by Aldehyde Oxidase

“…One document provided characterization data . Deuterated Bredereck’s reagent ( t -BuO)­CD­(NMe 2 ) 2 had also been reported, but there were no details provided regarding the preparation or characterization of this substance . A report describing the preparation and use of Me 2 N 13 CD­(OMe) 2 was more informative .…”