ChemInform Abstract: Mn(III)‐Based Reaction of Alkenes with Quinolinones. Formation of Peroxyquinolinones and Quinoline‐Related Derivatives.

Abstract

Mn(III)-Based Reaction of Alkenes with Quinolinones. Formation of Peroxyquinolinones and Quinoline-Related Derivatives. -The Mn(III)-promoted aerobic oxidation of alkenes in the presence of 4-hydroxyquinolin-2(1H)-ones under different reaction conditions is examined resulting in the formation of various types of quinoline derivatives. The process is extended to the synthesis of quinoline-related heterocycles with similar success. -(NISHINO*, H.; KUMABE, R.; HAMADA, R.; YAKUT, M.; Tetrahedron 70 (2014) 7, 1437-1450, http://dx.