2015
DOI: 10.1002/chin.201533201
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ChemInform Abstract: Monofluoromethylation of Tetrahydroisoquinolines by Visible‐Light Induced Direct C(sp3)—H Bond Activation.

Abstract: C‐1‐monofluoromethylated tetrahydroisoquinolines are obtained by visible‐light photoredox‐catalyzed reaction of tetrahydroisoquinolines with β‐fluorinated gem‐diols as CF‐source under mild reaction conditions.

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“…[21][22][23][24] TMDCs are layered 2D materials with a bandgap of up to ≈2 eV and charge carrier mobility values exceeding 150 cm 2 Vs À1 . [25,26] Corresponding field effect transistors (FETs) have shown excellent performance, with on-currents up to 1 mA mm À1 , on-off ratios above 10 8 , a subthreshold swing close to the physical limit of 60 mV dec À1 , and the possibility to realize nanometer-sized transistor channels. [27][28][29] TMDCs also have high mechanical resistance against strain, with Young's moduli up to 200 GPa.…”
Section: Introductionmentioning
confidence: 99%
“…[21][22][23][24] TMDCs are layered 2D materials with a bandgap of up to ≈2 eV and charge carrier mobility values exceeding 150 cm 2 Vs À1 . [25,26] Corresponding field effect transistors (FETs) have shown excellent performance, with on-currents up to 1 mA mm À1 , on-off ratios above 10 8 , a subthreshold swing close to the physical limit of 60 mV dec À1 , and the possibility to realize nanometer-sized transistor channels. [27][28][29] TMDCs also have high mechanical resistance against strain, with Young's moduli up to 200 GPa.…”
Section: Introductionmentioning
confidence: 99%