ChemInform Abstract: NEW APPROACH TO THE SYNTHESIS OF DIGLYCEROPHOSPHATE, THIONOPHOSPHATE, AND PHOSPHONATE STRUCTURES

Predvoditelev, D. A.; Chukbar, T. G.; Нифантьев, Э. Е.

doi:10.1002/chin.197620289

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2005

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“…The threefold molar excess of phosphorylating agent ( II ) was used to increase yield of the reaction product ( III ). The phosphorylating agent ( II ) excess was removed by distillation after the end of reaction [23]. The formation of dimethylamidophosphite ( III ) was monitored by TLC and 31 P NMR spectroscopy (see the Experimental section).…”

Section: Resultsmentioning

confidence: 99%

The Synthesis of Thio- and Selenoanalogues of Phospholipids on the Basis of 2-Butyl-2-Hydroxymethyl-1,3-Propanediol

Савин

Kutsemako

2005

Russ J Bioorg Chem

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New analogues of nonglycerol polyol phospholipids were prepared on the basis of 1,1,1-trimethylolethane. Amidophosphites and cyclophosphites of the isopropylidene derivative of this polyol were intermediates in the syntheses. They were treated with sulfur or selenium. Phosphoacetals were converted into lipids by the direct acylation with higher fatty acid chlorides. The triol bicyclophosphite was also used in the lipid syntheses. It was directly acylated at the oxygen atom, the resulting acylpolyol of chlorophosphite was then converted into phospholipids by alcoholysis and subsequent treatment with sulfur.

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Section: Resultsmentioning

confidence: 99%

The Synthesis of Thio- and Selenoanalogues of Phospholipids on the Basis of 2-Butyl-2-Hydroxymethyl-1,3-Propanediol

Савин

Kutsemako

2005

Russ J Bioorg Chem

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ChemInform Abstract: NEW APPROACH TO THE SYNTHESIS OF DIGLYCEROPHOSPHATE, THIONOPHOSPHATE, AND PHOSPHONATE STRUCTURES

Abstract: Isopropylidenglycerin (I) und das Triamid (II) setzen sich zum Di= äthylamid des Di‐isopropylidenglycerylphosphits (III) um, dessen Acidolyse das saure Phosphit (IV) liefert.

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The Synthesis of Thio- and Selenoanalogues of Phospholipids on the Basis of 2-Butyl-2-Hydroxymethyl-1,3-Propanediol

The Synthesis of Thio- and Selenoanalogues of Phospholipids on the Basis of 2-Butyl-2-Hydroxymethyl-1,3-Propanediol

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