ChemInform Abstract: Palladium‐Catalyzed Allylic Substitution of Secondary Allylic Esters with Ketone Enolates.

Abstract

Enolates. -The Pd-catalyzed allylic substitution of phosphate esters with lithium enolates proceeds regioselectively. Retention of the stereochemistry is observed for the enantiomerically enriched substrate ((R)-I). -(KINOUCHI, W.; SAEKI, R.; KAWASHIMA, H.; KOBAYASHI*, Y.; Tetrahedron Lett. 56 (2015) 17, 2265-2268, http://dx.