ChemInform Abstract: Phosphaalkene Derivatives of Furan and Thiophene: Synthesis, Crystal Structure, Electrochemistry and EPR Study of Their Radical Anions.

Abstract

Phosphaalkene Derivatives of Furan and Thiophene: Synthesis, Crystal Structure, Electrochemistry and EPR Study of Their Radical Anions.-The title compounds (I) undergo quasi-reversible reduction. The radical anions can be generated chemically by reaction at 255 K with a potassium mirror. The EPR study is carried out both in the liquid and solid state. Quantum mechanic calculations are performed. -(JOUAITI, A.; AL BADRI, A.; GEOFFROY, M.; BERNARDINELLI, G.; J.