ChemInform Abstract: PHOTOZERS. EINES DDT‐ANALOGEN

Liu, H. J.; Silk, Peter J.; Unger, I.

doi:10.1002/chin.197218168

Chemischer Informationsdienst

1972

DOI: 10.1002/chin.197218168

|View full text |Cite

ChemInform Abstract: PHOTOZERS. EINES DDT‐ANALOGEN

H. J. Liu¹,

Peter J. Silk²,

I. Unger³

Abstract: Das Diaryltrichloräthan (III) wird analog wie DDT aus dem Anisol (I) (aus p‐Chlorphenol und Methyljodid in Gegenwart von K‐carbonat) und Chloralhydrat (II) dargestellt.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1972

Publication Types

Select...

Article1

Relationship

Self Cite1

Independent0

Authors

Journals

Cited by 1 publication

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

The Photodecomposition of an Analogue of DDT

Liu¹,

Silk²,

Unger³

1972

Can. J. Chem.

Self Cite

View full text Add to dashboard Cite

The photodecomposition of 1,1,1-trichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPA) has been carried out both in solution and solid phase with exciting light > 300 nm. The major products of the solid phase photolyses are HCl and 1,1-dichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethylene (MPE), 5,5′-chloro-2,2′-methoxybenzophenone (MPO), 1,1-dichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPD), and 1-chloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPC). In liquid phase and in the presence of O2 the photodecomposition yields many products, the major ones, in addition to HCl, being MPE, MPD, MPC, and MPO. In the absence of O2 in liquid phase only HCl, MPD, MPC, and MPE were observed. In the O2 free photolysis MPD and MPC are produced in larger quantity than MPE. A preliminary investigation has shown that MPE irradiated at λ > 300 nm also photodecomposes. A check carried out by the Canada Department of Agriculture indicates that MPA is a pesticide although it may not be as effective as DDT.

show abstract

The Photodecomposition of an Analogue of DDT

Liu¹,

Silk²,

Unger³

1972

Can. J. Chem.

Self Cite

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

ChemInform Abstract: PHOTOZERS. EINES DDT‐ANALOGEN

Abstract: Das Diaryltrichloräthan (III) wird analog wie DDT aus dem Anisol (I) (aus p‐Chlorphenol und Methyljodid in Gegenwart von K‐carbonat) und Chloralhydrat (II) dargestellt.

Cited by 1 publication

References 1 publication

The Photodecomposition of an Analogue of DDT

The Photodecomposition of an Analogue of DDT

Contact Info

Product

Resources

About