Abstract:The photodecomposition of 1,1,1-trichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPA) has been carried out both in solution and solid phase with exciting light > 300 nm. The major products of the solid phase photolyses are HCl and 1,1-dichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethylene (MPE), 5,5′-chloro-2,2′-methoxybenzophenone (MPO), 1,1-dichloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPD), and 1-chloro-2,2-bis(5′-chloro-2′-methoxyphenyl)ethane (MPC). In liquid phase and in the presence of O2 the… Show more
Das Diaryltrichloräthan (III) wird analog wie DDT aus dem Anisol (I) (aus p‐Chlorphenol und Methyljodid in Gegenwart von K‐carbonat) und Chloralhydrat (II) dargestellt.
Das Diaryltrichloräthan (III) wird analog wie DDT aus dem Anisol (I) (aus p‐Chlorphenol und Methyljodid in Gegenwart von K‐carbonat) und Chloralhydrat (II) dargestellt.
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