ChemInform Abstract: REACTIONS OF METHYL FLUOROSULPHONATE AND TRIETHYLOXONIUM TETRAFLUOROBORATE WITH METAL COMPLEXES

EABORN, C.; Farrell, N.; Murphy, James L.; Pidcock, Alan

doi:10.1002/chin.197347215

Chemischer Informationsdienst

1973

DOI: 10.1002/chin.197347215

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ChemInform Abstract: REACTIONS OF METHYL FLUOROSULPHONATE AND TRIETHYLOXONIUM TETRAFLUOROBORATE WITH METAL COMPLEXES

C. EABORN¹,

N. Farrell²,

James L. Murphy³

et al.

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1979

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“…Halogen abstraction from [PtCl,(PR,),] by MeS0,F produces the related halide-bridged binuclear complexes, [Pt, (p-Cl) ( PR,),] [SFO,] 2. 6 Further evidence for the formulation of the binuclear complexes was derived from two bridge-splitting reactions performed on solutions of the complex before decomposition progressed. Treating the complex with [NEt,]Cl regenerated the original carbene complex.…”

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Reactions of electroneutral alkoxy(organo)carbene complexes of platinum(II)

Anderson¹,

Cross²

1979

J. Chem. Soc., Dalton Trans.

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The carbene complexes cis-[PtCI,(PR,)(C(OR')(CH,R"))](1 ; R, = Me,Ph or Et,; R' = Me, Et, or Pr"; R" = Me, Et, or Ph) react rapidly with CD,OD to yield cis-[PtCI,(PR,){C(OR') (CD,R"))], then slowly by alkoxy-group exchange to cis-[PtCI,(PR,)(C(OCD,) (CD,R"))].Dimethylamine reacts by proton abstraction to form [PtCI-(PR,) (NMe,H){C(OR')=CHR"}].The carbene complexes react with chloride ions by R'CI elimination to form the acyls [Pt?(p-CI),(PR,),(COCH,R"),].Thermolyses of (1 ) produce the same products. These reactions are compared with those of related cationic carbene complexes. Treatment of (1) by PR, in the presence of Ag-[S(CF,)O,] leads to the cationic carbene complex trans-[PtCI(PR,),(C(OR')(CH,R"))] [S(CF,)O,] which can also be made by the action of R'SO,CF, on trans-[PtCI(PR,),(COCH,R")].

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confidence: 99%

Reactions of electroneutral alkoxy(organo)carbene complexes of platinum(II)

Anderson¹,

Cross²

1979

J. Chem. Soc., Dalton Trans.

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ChemInform Abstract: REACTIONS OF METHYL FLUOROSULPHONATE AND TRIETHYLOXONIUM TETRAFLUOROBORATE WITH METAL COMPLEXES

Cited by 1 publication

References 1 publication

Reactions of electroneutral alkoxy(organo)carbene complexes of platinum(II)

Reactions of electroneutral alkoxy(organo)carbene complexes of platinum(II)

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