Chemischer Informationsdienst. Organische Chemie
 1971
DOI: 10.1002/chin.197102211
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ChemInform Abstract: REDUKTONE UND TRICARBONYLVERBINDUNGEN 25. MITT. 1,2‐VERSCHIEBUNG VON CARBONESTERGRUPPEN BEI DER BENZILSAEUREUMLAGERUNG VON ALPHA,BETA‐DIOXO‐BUTTERSAEUREESTERN

H. Dahn1,
Heike Gowal2,
H.-P. Schlunke3

Abstract: Unter der Einwirkung von wäßriger NaOH wandert die intakte Estergruppe des schwer verseifbaren Esters (I) an das C‐Atom der β‐Carbonylgruppe unter Bildung des Tartronsäureesters (II), der beim Erhitzen zum Hydroxyester (III) decarboxyliert wird.

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