ChemInform Abstract: Sulfur Diimide, S(NH)₂, and Monosubstituted Sulfur Diimides, S(NR)(NH), with R: tert.‐Butyl and Trimethylsilyl.

Abstract

Durch stöchiometrische Protonierung des Anions SN%′ in K2SN2 mit Essigsäure wird die instabile Verbindung (I) in Lösung erhalten.

The first stable RNSNH sulfur diimide

“…Seemingly for the same reason, monosubstituted R-N=S=N-H derivatives have neither been isolated nor unambiguously characterised. 2,3 This work deals with the synthesis and X-ray structural characterization of first stable R-N=S=N-H sulfur diimide 1 (R = 2,4,6-Bu t 3 C 6 H 2 S).…”