ChemInform Abstract: SYNTHESES AND STRUCTURE ANALYSES OF IODOCUPRATES(I). VI. IODOCUPRATES(I) WITH H DINUCLEAR ANIONS (CU2I4)2‐ AND (CU2I6)4‐

Abstract

Durch Umsetzung von Cu‐ Pulver mit I, und [PyzCHzllz oder [PPh4]l in Aceton werden [Py2CH2]2[Cu216] (I) und zwei Modifikationen von,[Ph4P]2[Cu2I4] (IIa) und (IIb) erhalten.

Multiple structural variants of LnCuI(.mu.-X)2CuILn (n = 1, 2). Influence of halide on a "soft" potential energy surface

“…1028 ( 6) 830( 5) 717 ( 7) 14( 12) H( 16) 1036 (5) 939 (4) 681 (6) 0( 10) H( 17) 777 ( 8) 866 (5) 548 (9) 33( 15) H( 18) 821 ( 6) 903 (4) 414( 7) 15 (12) H( 19) 823 (6) 687 (5) 496 ( 7)…”

“…System 2 is thus especially soft (i.e., associated with a fiat potentia I surface for distortion of the rhombus), and several structures (or a nearcontinuum) are possible for such systems and intermolecular forces can stabilize the rhombus with a large variety of internal are numerous examples of such distortion in the series Cu2X42and one reported example in the case of Cu2l64 . !0 12 The degree of this distortion varies greatly. The reason for a distortion of this sort can be understood from the above analysis.…”

Iodoargentates and Cuprates Stabilized by Sulfonium Cations With Long Alkyl Chains

“…In the case of iodocuprates, several examples of structures containing CuI 3 groups are known in compounds such as methyltriphenylphosphonium triiodocuprate [17] or cobaltocenium triiodocuprate. [18] Additionally, similar compounds for Cu II , containing the CuX 3 Ϫ anion (X ϭ Cl, Br), have been published recently. [19] The CuX 3 Ϫ conformation deviates from a perfect trigonal structure, as expected, due to potential JahnTeller instability.…”

[Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5− and [Cu12I15]3− clusters

“…The bond lengths and angles are comparable to those found in similar copper(I) iodide clusters. [11][12][13][14][15][16][17] Unlike most halometallate compounds, the title compound has a transition metal-containing cation, [Co(phen) 3 ] 2+ , which has previously been used by our group as the charge-balancing cation in solvothermally synthesized halometallate compounds. 31 This cation contains a Co 2+ center complexed by three bidentate 1,10-phenanthroline ligands, resulting in a slightly distorted octahedral coordination environment (Fig.…”

“…[5][6][7][8][9][10][11] Among these, the iodocuprates have been extensively investigated; and the work, in particular, of Hartl and co-workers, has resulted in the syntheses and structural characterizations of a large number of copper(I) iodide clusters, including: Cu 5 I 7 . [12][13][14][15][16][17][18] In this paper we report on the preparation and structures of two, previously unreported copper(I) iodide halometallate clusters, Cu 10 I 15 5À and Cu 12 I 15 3À , in [Co(phen 3 )] 2 [Cu 11 I 15 ] and on the extensive edge-to-face and offset face-to-face interactions between the [Co(phen 3 )] 2+ cations.…”