Chemischer Informationsdienst
 1982
DOI: 10.1002/chin.198211197
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ChemInform Abstract: SYNTHESIS OF 2,2‐DIMETHYL‐1‐CARBAPENAM DERIVATIVES VIA AN INTRAMOLECULAR MICHAEL‐TYPE REACTION

M. Shibuya1,
Masahiko Kuretani2,
S. KUBOTO3

Abstract: Aus der 3,3‐Dimethyl‐4‐pentensäure (Ia) erhält man über das Säurechlorid (Ib) mit Lithioessigsäureethylester (II) den ungesättigten Ketoester (III), der nach Cyclisierung mit Hydroxylamin zu (IV) reduktiv zum Aminocarbonsäureester (V) gespalten und verestert wird.

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