ChemInform Abstract: SYNTHESIS OF TETRACHLOROMETHYLENEDIPHOSPHINE AND ITS DERIVATIVES

Abstract

Das Diphosphin (III) erhält man aus Phosphortrichlorid und Methylen‐bis‐ aluminiumdichlorid über den Komplex (II).

Iron(0) and ruthenium(0) complexes with tridentate phosphonite ligands and their potential for ketene formation from methyl iodide, CO and a base

“…Essentially two methods have been applied to introduce alkoxy substituents on a phosphorus atom: the alcoholysis of aminophosphine derivatives [6][7][8][9][10] or the reaction of chlorophosphine derivatives with an alcohol in the presence of a tertiary amine base [11][12][13][14][15]. Triphosphine ligands of the type RP[CH 2 CH 2 CH 2 P(OR) 2 ] 2 have not been reported previously.…”

Backbone modified small bite-angle diphosphines: Synthesis and molecular structures of [M(CO)4{X2PC(R1R2)PX2}] (M=Mo, W; X=Ph, Cy; R1=H, Me, Et, Pr, allyl, R2=Me, allyl)

“…In contrast, carbon-linked varieties are predominantly functionalised at phosphorus [41][42][43][44][45][46][47][48][49][50][51][52][53][54][55][56][57], with backbone functionalisation being far less widely studied [58][59][60][61][62][63][64]. This is due to the synthetic methods widely utilised (Eqs.…”

An Unusual Oxidation of 1,5-Dimethyl-2,4-bis(dialkylamino)-1,5-diaza-2,4-diphosphinan-6-one with Hexafluoroacetone

“…The digital resolutions were 0.25 Hz, 0.5 Hz and 1.25 Hz for 1 H-, 13 C-and 31 P NMR spectra respectively. 3a,b: Compounds 3a,b can be obtained with a 35Ϫ40% yield (after distillation) from methylene-bis(dichlorophosphane) [17] and dialkylamine. Use of silylated dialkylamine increases the yield to 50%.…”