ChemInform Abstract: Transformation of Carboxylic Esters to Aldehydes with Sodium Tris( diethylamino)aluminum Hydride.

Abstract

1995 reduction, hydrogenation reduction, hydrogenation O 0220 28 -063 Transformation of Carboxylic Esters to Aldehydes with Sodium Tris( diethylamino)aluminum Hydride. -The new reducing reagent, sodium tris(diethylamino)aluminum hydride reduces esters to aldehydes more selectively and under milder conditions than lithium tris(diethylamino)aluminum hydride. -(CHA, J. S.; KIM, J. M.; JEOUNG, M. K.; KWON, O. O.; KIM, E. J.; Org. Prep. Proced. Int. 27 (1995) 1, 95-98; Dep. Chem., Yeungnam Univ., Kyongsan 712-749, S. Korea; EN)

Regiospecific Ring-Opening of Unsymmetrical Epoxides to the Corresponding Less Substituted Alcohols by Newly-Devised Meerwein-Ponndorf-Verley Type Reagents

“…[25][26][27][28][29] Furthermore, hydroxy-, alkoxy-, acetoxyand methanesulfonyl-incorporated diisopinocampheylborane derivatives (12)(13)(14)(15)(16)(17) were prepared and their applicability in MPV type reduction was explored. [30][31][32][33][34][35][36]…”