Chemischer Informationsdienst. Organische Chemie
 1970
DOI: 10.1002/chin.197016214
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ChemInform Abstract: UNTERSUCHUNGEN IN DER CYCLOBUTANREIHE 26. MITT. VERSUCHE ZUR SYNTH. VON 1‐TERT.‐BUTYL‐BENZOCYCLOBUTADIEN UND 1,2‐DI‐TERT.‐BUTYL‐BENZOCYCLOBUTADIEN

Margarete Avram1,
Doina Constantinescu2,
I. G. Dinulescu3
et al.

Abstract: trans‐1,2‐Dibrom‐benzocyclobuten (I) reagiert mit tert.‐Butylmagnesiumchlorid (II) zu den beiden Substitutionsprodukten (III) und (IV) (III) Wurde durch N‐Brom‐succinimid zu (V) substituiert; bei der Dehydrobromierung von (V) entsteht nur intermediär das Cyclobutadien (VI), es wird dessen Dimeres (VII) isoliert.

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