CHEMISTRY OF OXOMOLYBDENUM(V) AND (VI) COMPLEXES INCORPORATING OXYGEN, NITROGEN, AND/OR SULFUR DONOR ATOMS. II. SYNTHESIS AND CHARACTERIZATION OF SOME HETEROLEPTIC DIOXOMOLYBDENUM(VI) COMPLEXES OF THE TYPE [MoO2Cl(L)L'] (L=DITHIOCARBAMATES OR XANTHATES AND L'=OPPh3 AND DMSO)

Nag, Purnima; Bohra, Rakesh; Mehrotra, R. C.; Ratnani, Raju

doi:10.1081/sim-120015079

Cited by 8 publications

(1 citation statement)

References 13 publications

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“…In continuation to our previous work [14, 23, 24, 25, 26] and to further study the chemistry of oxomolybdenum complexes incorporating oxygen, nitrogen and sulphur donor atoms; the synthesis of dioxomolybdenum(VI) complexes with internally functionalized oximes and Schiff's bases derived from β-diketones is reported in present work.…”

Section: Introductionmentioning

confidence: 53%

Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]

Nag

Sharma

2019

Heliyon

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Interaction of [MoO 2 (acac) 2 ] with internally functionalized oximes like HON=C(CH 3 )Ar (Ar = C 4 H 3 S, C 4 H 3 O or C 5 H 4 N) and Schiff's Bases derived from β – diketones like HOC(R)CHC(R′)=NC 6 H 5 (R = R’ = CH 3 or C 6 H 5 ; R = CH 3 and R’ = C 6 H 5 ) led to the formation of yellow dioxomolybdenum(VI) complexes of the type [MoO 2 {ON=C(CH 3 )Ar} 2 ] and [MoO 2 {OC(R)CHC(R′)=NC 6 H 5 } 2 ]. Oximes were synthesized by green methodology. The newly synthesized complexes were characterized on basis of elemental analysis and various spectral findings. Anticandidal activity of [MoO 2 {ON=C(CH 3 )C 6 H 4 N} 2 ] clearly reveals that the complex is biologically active against fungal diseases.

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Section: Introductionmentioning

confidence: 53%

Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]

Nag

Sharma

2019

Heliyon

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Synthesis, structural and catalytic activity of binaphthyl macrocyclic complexes

Hanafy

Maki

Mostafa

2007

Transition Met Chem

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The binaphthyl macrocyclic ligand, N,N¢-diethyl-[3,3¢-(2,2¢-dihydroxy-1,1¢-binaphthyl)carboxamide]-2,2¢-dihydroxy-1,1¢-binaphthyl-3,3¢-dicarboxylic acid (DDCDB), has been synthesized and investigated. The ligand (DDCDB) and its metal complexes involving Cu II , Zn II , UO 2 II , Th IV , Ce III , Mo VI and W VI ions have been prepared and characterized by spectral (i.r., u.v.-vis.), elemental analyses, magnetic moments and thermal analyses measurements. DDCDB behaves as a tridentate ligand towards Cu II , Zn II and UO 2 II ions coordinating via CO, NH and the deprotonated naphthyl OH groups in a ratio of 2:1 (M:L). On the other hand, DDCDB behaves in a bidentate manner coordinatingvia the NH and the deprotonated naphthyl OH groups only in case of the Th IV , Ce III , Mo VI , and W IV ions and in ratio 1:1 (M:L). Results of thermal measurements confirm the existence of solvent molecules inside and outside the coordination sphere. Th VI complex has been applied for the hydrolysis of phosphodiester and the results show a significant rate enhancement of $5.8 million fold with respect to the auto-hydrolysis of bis-(p-nitrophenyl) phosphate (BNPP) under the same conditions Also, Cu II complex accelerates the photodegradation of the hazardous pollutant (acid green dye) in the presence of hydrogen peroxide by degrading 90% of the dye within 23 min.

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Bio-inspired Mo(II) complexes as active catalysts in homogeneous and heterogeneous olefin epoxidation

Fernandes

Silva

Vaz

et al. 2010

Applied Catalysis A: General

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CHEMISTRY OF OXOMOLYBDENUM(V) AND (VI) COMPLEXES INCORPORATING OXYGEN, NITROGEN, AND/OR SULFUR DONOR ATOMS. II. SYNTHESIS AND CHARACTERIZATION OF SOME HETEROLEPTIC DIOXOMOLYBDENUM(VI) COMPLEXES OF THE TYPE [MoO2Cl(L)L'] (L=DITHIOCARBAMATES OR XANTHATES AND L'=OPPh3 AND DMSO)

Cited by 8 publications

References 13 publications

Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]

Synthesis, characterization and anticandidal activity of dioxomolybdenum(VI) complexes of the type [MoO2{ON=C(CH3)Ar}2] and [MoO2{OC(R)CHC(R’)=NC6H5}2]

Synthesis, structural and catalytic activity of binaphthyl macrocyclic complexes

Bio-inspired Mo(II) complexes as active catalysts in homogeneous and heterogeneous olefin epoxidation

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