Chemoenzymatic Synthesis of Idesolide from Benzoic Acid

Hudlický, Tomáš; Adams, David R.; Aichinger, Christian; Rinner, Uwe

doi:10.1055/s-0030-1259694

Cited by 3 publications

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Benefits of Unconventional Methods in the Total Synthesis of Natural Products

Hudlický

2018

ACS Omega

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This article provides a survey of four “unconventional” methods employed in the synthesis of natural products in the Hudlicky group. The utility of flash vacuum pyrolysis is highlighted by examples of many natural products attained via vinylcyclopropane–cyclopentene rearrangement and its heterocyclic variants. Preparative organic electrochemistry was used in oxidations and reductions with levels of selectivity unattainable by conventional methods. Yeast reduction of ketoesters was featured in the total synthesis of pyrrolizidine alkaloids. Finally, the use of toluene dioxygenase-mediated dihydroxylations in enantioselective synthesis of natural products concludes this presentation. Recently, synthesized targets in the period 2010–2019 are listed in the accompanying table. The results of research from the Hudlicky group are placed in appropriate context with the work of others, and a detailed guide to the current literature is provided.

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Benefits of Unconventional Methods in the Total Synthesis of Natural Products

Hudlický

2018

ACS Omega

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Remote sensing with nonlinear negative-index metamaterials

Popov

Myslivets

2014

SPIE Proceedings

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A concept of the remotely actuated and interrogated four-wave mixing photonic sensor, which employs the negative-index photonic materials, is described. Unique electromagnetic properties of such a metamaterial enable enhancement of frequency conversion and redirection of the signals which carry important information for environmental probing. Four-wave mixing process allows for independent engineering of resonantly enhanced optical nonlinearities and negative refractive index.Keywords: Optical remote sensing, optical frequency up-conversion and parametric amplification, negative refractive index metamaterials, backward electromagnetic waves, infrared nonlinear optical microsensors.

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