2021
DOI: 10.1021/jacs.1c06572
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Chemoselective Electrosynthesis Using Rapid Alternating Polarity

Abstract: Challenges in the selective manipulation of functional groups (chemoselectivity) in organic synthesis have historically been overcome either by using reagents/catalysts that tunably interact with a substrate or through modification to shield undesired sites of reactivity (protecting groups). Although electrochemistry offers precise redox control to achieve unique chemoselectivity, this approach often becomes challenging in the presence of multiple redox-active functionalities. Historically, electrosynthesis ha… Show more

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Cited by 116 publications
(83 citation statements)
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“…It is also highly toxic. The extraction of uranium and the development of nuclear power can produce hazardous and radioactive waste [1][2][3][4][5]. Consequently, uranium separation and recovery are important processes in terms of both uranium resource exploitation and environmental preservation.…”
Section: Introductionmentioning
confidence: 99%
See 4 more Smart Citations
“…It is also highly toxic. The extraction of uranium and the development of nuclear power can produce hazardous and radioactive waste [1][2][3][4][5]. Consequently, uranium separation and recovery are important processes in terms of both uranium resource exploitation and environmental preservation.…”
Section: Introductionmentioning
confidence: 99%
“…Recent progress in uranium(VI) ion sorption from contaminated water has been conducted using various sorbents such as organic materials, e.g., cellulose/chitosan-based sorbent materials [1-5], functionalized synthetic polymers [1,10], hydrogel [11], and aerogel [12]. Moreover, porous materials have been widely studied in the field of uranium extraction from seawater [1][2][3]. Clays, metal oxides, and AL-based LDH are examples of inorganic materials [13].…”
Section: Introductionmentioning
confidence: 99%
See 3 more Smart Citations