Chiral binaphthylamine based emitters with donor-acceptor structures: Facile synthesis and circularly polarized luminescence

Chiral TADF Polymers Realizing Highly‐Efficient Deep‐Red Circularly Polarized Electroluminescence Over 660 nm

“…M2 and R/S-1 were easily prepared according to the reported method (Scheme 1). [54,68] The chiral monomers R/S-M1 were prepared from reported enantiomers R/S-1 through a two-step synthesis as the procedure given in Supporting Information. The structures and the average molecular weight of the polymers were confirmed after characterization by 1 H NMR and gel permeation chromatography (GPC), respectively.…”

Construction of Circular Polarized Luminescence Molecules for Intense Near Infrared OLEDs

“…These properties facilitate the generation of larger g lum and enable the acquisition of distinct attributes, such as aggregation‐induced emission (AIE) and thermally activated delayed fluorescence (TADF). [ 44 ] Chen et al developed the chiral donor–acceptor (D*‐A) polymers R ‐P and S ‐P CP‐PLED devices, which exhibited external quantum efficiencies (EQEs) of 6.2% and 5.8% at 662 nm, and electroluminescence dissymmetry factors of +1.6 × 10 −3 and −1.7 × 10 −3 . [ 45 ] Yang et al also designed a pair of D–A type multifunctional chiral TADF small molecules R/S ‐DOBP , which showed a high EQE of 1.9% at 716 nm and obvious circular dichroism (CD) and CPL signals in the solution.…”

Electrochemical Synthesis of 1,1′-Binaphthalene-2,2′-Diamines via Transition-Metal-Free Oxidative Homocoupling

“…1,1 -Bi-2-naphthylamine (BINAM) and its derivatives are widely used as building blocks for transition-metal ligands and organocatalysts [1][2][3][4], as well as chiroptical materials for fluorescence sensing [5][6][7]. Among their syntheses, transition-metal mediated coupling of 2-naphthylamine derivatives has been well established [8][9][10][11][12].…”