We report a detailed electronic structure calculation for Vanadium (V) using DFT, DFT+U , G0W0, GW0 and DFT+DMFT methods. The calculated values of W , U and J by cRPA method are ∼1.1, ∼3.4 and ∼0.52 eV, respectively. The comparison between calculated spectra (CS) and experimental spectra (ES) suggests that W (U ) is more accurate for DFT+U (DFT+DMFT) method. The CS, obtained by these methods, give fairly good agreement with ES for peaks' positions except GW0. The shallowness of the dips lying ∼ -1.5 eV and ∼1.0 eV in ES are properly explained by DFT+DMFT method only, due to the presence of incoherent t2g states. This work suggests that for the proper explanation of ES, sophisticated many-body theory is needed even for the simple metal.