Chlorobis(1,10-phenanthroline)copper(II) chloride methanol solvate 4.5-hydrate

Chlorobis(1,10-phenanthroline-κ2 N,N′)copper(II) dicyanamide

“…The dca anion, which has a twofold rota-tion axis passing through N3, does not enter the inner coordination sphere. In the trigonal bipyramid, the two axial Cu1-N10 [1.9956 (18) Å ] bonds are almost collinear and are shorter by 0.106 Å than the two equatorial Cu1-N20 [2.1018 (13) Å ] bonds (Table 1), which is a feature generally observed for compounds with the [Cu(L-L) 2 Cl] + cation, where L-L = bpy (O'Sullivan et al, 1999;Jia et al, 2005) or phen (Murphy et al, 1998;Lu et al, 2004).…”

Synthesis, crystal structure and action on Escherichia coli by microcalorimetry of copper complexes with 1,10-phenanthroline and amino acid

“…The four N of the two phen ligand and Cu were not in a plane, and the angles of N 1 -Cu 1 -N 3 and N 2 -Cu 1 -N 4 are about 120°a nd 175°, respectively [43,44]. The dihedral angle between two phen of complex 5 is larger than 50°.…”

Combining a Phenanthroline Moiety with Peralkylated Guanidine Residues: Homometallic CuII, NiII and ZnII Halide Complexes with Site‐Differentiating Janus Head Ligands

“…Whereas the [Cu(N ··· N) 2 X] + (X = Cl and Br) structural motif found in complexes 1 – 4 is also present in a variety of other metalated phenanthrolines including systems with extended aromatic frameworks, the electroneutral [Ni(N ··· N) 2 Cl 2 ] coordination site within complexes 5 and 6 is virtually unknown. Thus, 6 is the first nickel(II) complex with two coordinated phenanthroline units and two chloride ions stable as a discrete molecule.…”