1973
DOI: 10.1021/ic50125a004
|View full text |Cite
|
Sign up to set email alerts
|

Circular dichroism of amino acid complexes of nickel(II)

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2

Citation Types

0
4
0

Year Published

1973
1973
2021
2021

Publication Types

Select...
5
1

Relationship

0
6

Authors

Journals

citations
Cited by 13 publications
(4 citation statements)
references
References 2 publications
0
4
0
Order By: Relevance
“…Significant changes in the ECD spectra of amino 18–22 and hydroxycarboxylic acid (HCA) 23 solutions were observed in the presence of transition metal ions as a result of complexation. In addition to structural changes (chelate ring formation), coordination of an optically active molecule (ligand) to a transition metal ion induces rotational strength into its d–d electronic transitions which gives rise to new ECD signals 18–22 . This phenomenon has been recently exploited in a novel chiroptical ee sensing technique which is based on the detection of induced visible ECD bands by complexation of transition metal ions with chiral organic analytes 24,25 .…”
Section: Introductionmentioning
confidence: 99%
See 2 more Smart Citations
“…Significant changes in the ECD spectra of amino 18–22 and hydroxycarboxylic acid (HCA) 23 solutions were observed in the presence of transition metal ions as a result of complexation. In addition to structural changes (chelate ring formation), coordination of an optically active molecule (ligand) to a transition metal ion induces rotational strength into its d–d electronic transitions which gives rise to new ECD signals 18–22 . This phenomenon has been recently exploited in a novel chiroptical ee sensing technique which is based on the detection of induced visible ECD bands by complexation of transition metal ions with chiral organic analytes 24,25 .…”
Section: Introductionmentioning
confidence: 99%
“…Significant changes in the ECD spectra of amino 18–22 and hydroxycarboxylic acid (HCA) 23 solutions were observed in the presence of transition metal ions as a result of complexation. In addition to structural changes (chelate ring formation), coordination of an optically active molecule (ligand) to a transition metal ion induces rotational strength into its d–d electronic transitions which gives rise to new ECD signals 18–22 .…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…complexes have been reported. 43 Such compounds show two peaks for the ν 2 transition as well, but they have the opposite sign. This reversal of sign is presumably associated with the different coordination modes of the amino acids.…”
mentioning
confidence: 99%