cis-Aconitic Acid at 150K

Nagel, Norbert; Endruschat, U.; Bock, H.

doi:10.1107/s0108270196008220

Cited by 3 publications

(1 citation statement)

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“…With consideration of these factors, attack of phosphine on the β‐carbon atom of maleic acid (path b) is more preferable than α‐attack (path a ), taking into account equal steric hindrance of the α‐ and β‐centers (Scheme ). According to X‐ray data, cis ‐aconitic acid, as well as maleic acid, is prone to form an intramolecular hydrogen bond between the two carboxyl groups attached to the C=C bond, as shown in Scheme , structure G .…”

Section: Resultsmentioning

confidence: 99%

Effect of Anchimeric Assistance in the Reaction of Triphenylphosphine with α,β‐Unsaturated Carboxylic Acids

Salin

Fatkhutdinov

Il'in

et al. 2014

Int J of Chemical Kinetics

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Quaternization of triphenylphosphine with maleic and cis-aconitic acids is strongly accelerated by participation of the cis-carboxyl group in stabilization of the phosphonium zwitterion intermediate by intramolecular hydrogen bonding, in spite of steric hindrance by the acid's reaction center. A similar effect for trans-isomeric acids is not observed, which can be rationalized on the basis of spatial structures of the generated zwitterions, implying an electrostatic interaction between the phosphonium center and carbonyl oxygen atom. The effect of anchimeric assistance decreases when the intramolecular hydrogen bonding disfavors attack of the phosphine on the sterically less hindered carbon atom of the C=C bond, as observed for cis-aconitic acid. C

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Section: Resultsmentioning

confidence: 99%