Cleaner preparation of poly(vinylidene fluoride)/barium titanate composites: Thermal, mechanical, and dielectric properties and relaxation dynamics

Abstract

Traditional polymer composite preparation techniques often employ organic solvents, which can damage the environment, to disperse inorganic fillers. In this article, classic nanocomposites with poly(vinylidene fluoride) (PVDF) polymer matrices and BaTiO3 nanoparticle (BTP) fillers were created by a clean method combining planetary ball milling with an ultracentrifugal mill and then hot pressed into thin films. The microstructures, properties and relaxation dynamics of the thin films were characterized and analyzed. Scanning electron microscopy results demonstrated that BTP was homogeneously dispersed in the PVDF matrix. The thermal, mechanical, and dielectric properties were comparable to those of composite films prepared by solution mixing. Dielectric analysis revealed that the dielectric constant of the thin films reached 14 (104 Hz) when the volume fraction of BTP was 30%; however, the dielectric loss was 0.1 (104 Hz). Additionally, the dielectric loss spectra fitted with the Havriliak−Negami (H−N) and Vogel Fulcher equations were employed to analyze the relaxation dynamics of the nanocomposites. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47254.

High dielectric thin films based on barium titanate and cellulose nanofibrils

“…2 Excellent HDMs can signicantly cut down dissipation, improve the efficiency of energy storage, and shrink the size of devices. 3 Organic/inorganic composites are some of the most extensively studied HDMs as they combine the merits of both components, such as enhanced dielectric properties, outstanding thermal stabilities, bio-compatibility, light weight, low cost and remarkable processing properties. [4][5][6][7] Ferroelectric ceramics such as lead-free barium titanate (BaTiO 3 , BTO) have long been of interest as llers for high dielectric composites.…”