Recently, high-frequency devices for Ka band and above are becoming more important for wireless communication due to 5 G and beyond applications. The highfrequency AlGaN/GaN high-electron-mobility transistors (HEMTs) are widely considered for millimeter-wave applications due to high electron mobility, high critical field, excellent electron peak velocity, and wide bandgap of GaN material. [1][2][3][4] To reduce the production cost, AlGaN/GaN HEMTs grown on Si substrates are popularly investigated for Ka band applications. [5] Besides, the AlGaN/GaN HEMTs on Si technology has the potential to be integrated into complementary metaloxide-semiconductor (CMOS) circuits on the same platform. [6] Over the past, several GaN-based technologies for applications at Ka band or above have been reported. Demonstration of highefficiency monolithic microwave integrated circuits (MMIC) power amplifiers using 40 nm gate length technology was presented. [7] A 60 nm gate length with graded-channel technology was adopted, exhibiting peak power-added efficiency (PAE) up to 70%. [8,9] While the short gate length approaches effectively led to high efficiency at the desired frequency bands, the power density and overall reliability may be an issue due to the limited breakdown voltage. GaN-on-SiC configuration with very thin barrier of 3 nm was reported, showing a power density of 4 W mm À1 under continuous wave (CW) mode at 40 GHz. [10] In general, gold (Au) is used as the thick metallization metal for III-V HEMTs in the past. Moreover, the price of Au is expensive. To reduce the production cost for mass production of GaN-based device, copper (Cu) is considered to be an ideal candidate to replace Au as metallization metal. Compared to Au, Cu has lower resistivity, and the better thermal conductivity of Cu suggests it to be a suitable replacement. Nevertheless, when Cu is in direct contact with a semiconductor, it tends to diffuse into the semiconductor, sabotaging the substrate and the device. [11][12][13] Therefore, a diffusion barrier layer is needed to overcome this problem.Diffusion barrier layers such as tantalum (Ta), tantalum nitride (TaN x ), tungsten nitride (WN x ), Ta/MnSi x O y bilayer structures, and platinum (Pt) have been studied in the past years. [13][14][15][16][17] According to the previous reports, Pt is an effective diffusion barrier to prevent Cu diffusion into III-V devices. [8,12,13] Reports have also shown that addition of titanium (Ti) layer to the Au/WN x or WN x /Cu interfaces can improve the adhesion between Cu and the semiconductor. [18]