2015
DOI: 10.1016/j.jngse.2015.07.048
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CO 2 chemical absorption into aqueous solutions of piperazine: modeling of kinetics and mass transfer rate

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Cited by 34 publications
(18 citation statements)
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“…1,2 Many efforts have been done to develop various techniques for CO 2 removal including chemical absorption, physical absorption, physical adsorption, membrane separation, and cryogenic separation. 3,4 Among the various chemical and physical processes available for CO 2 removal, using aqueous solution of alkanolamines such as monoethanolamine and diethanolamine based absorption method is well known with signicant commercial application for CO 2 capture. 5,6 However, some drawbacks associated with liquid amine solutions for CO 2 separation such as extensive corrosion of equipment, high cost of amine, oxidative solvent degradation, large energy penalty for regeneration and loss of amine during regeneration are reasons which make it indispensable to see other alternative processes.…”
Section: Introductionmentioning
confidence: 99%
“…1,2 Many efforts have been done to develop various techniques for CO 2 removal including chemical absorption, physical absorption, physical adsorption, membrane separation, and cryogenic separation. 3,4 Among the various chemical and physical processes available for CO 2 removal, using aqueous solution of alkanolamines such as monoethanolamine and diethanolamine based absorption method is well known with signicant commercial application for CO 2 capture. 5,6 However, some drawbacks associated with liquid amine solutions for CO 2 separation such as extensive corrosion of equipment, high cost of amine, oxidative solvent degradation, large energy penalty for regeneration and loss of amine during regeneration are reasons which make it indispensable to see other alternative processes.…”
Section: Introductionmentioning
confidence: 99%
“…The final equation obtained according to Eq. (12)(13)(14) is presented according to which the predicted values were obtained. As it is known, the numerical coefficients of temperature and TEA concentration are negative, which indicates the negative effect of these parameters, as well as the numerical coefficient of the amount of activated carbon, which shows the positive influence of this parameter on CO 2 loading.…”
Section: Response Surface Methodology (Rsm)mentioning
confidence: 99%
“…Currently, chemical absorption of CO 2 with alkanolamines is the most common commercial method of high-efficiency separation in the industry. Chemical absorption by amine solvents is a reliable, well-established, and practical technique widely regarded as the most selective and promising of the various CO 2 removal technologies [12][13][14][15][16]. Conventional amine absorbents, on the other hand, have a significant energy demand for solvent regeneration.…”
Section: Introductionmentioning
confidence: 99%
“…Another advantage of MDEA is the low specific heat and heat of reaction with H 2 S and CO 2 , which reduces the energy consumption in the desorption process. By replacing DEA with MDEA, the energy consumption could be decreased up to 75 % [16,17].…”
Section: Introductionmentioning
confidence: 99%