Co(II), Ni(II), Cu(II) COMPLEXES WITH 1-NICOTINOIL-2-(2-HYDROXYBENZYL) HYDRAZINE

Abstract

By reduction of 1-nicotinoyl-(2-salicylidene)hydrazone with use NaBH 4 1-nicotinoyl-2-(2-hydroxybenzyl)hydrazine was obtained. Co(II), Ni(II), Cu(II) complexes with these ligands were synthesized and their structure was studied. It was shown that first ligand behaves as a dianionic tridentate, while second is monoanionic tridentate.

Copper(II) Complex with (E)-N ′ (3,5-di-tert-butyl-2-hydroxybenzilidene)-2-Hydroxybenzohydrazide

“…Previously, we have found that metal complexes of hydrazones of salicylic acid derivatives have signi cant inhibitory and urease activity [19]. At the same time, succinic and nicotinic acid hydrazones and their complexes have high bactericidal and fungicidal activity [20,21].…”

Copper(II) Complex With (E)-N′(3,5-Di-Tert-Butil-2-Hedroxybenzilidene)-2-Hydroxybenzohydrazide.

“…[14,15]. Previously, we found that metal complexes of hydrazones of salicylic acid derivatives have significant inhibitory and urease activity [16], succinic and nicotinic acid hydrazones and their complexes have high bactericidal and fungicidal activity [17,18].…”