It is shown that the critical current density of high-Tc wires can be greatly enhanced by using a threefold approach, which consists of grain alignment, doping, and optimization of the grain architecture. According to model calculations, current densities of 4 · 10 6 A/cm 2 can be achieved for an average grain alignment of 10• at 77 K. Based on this approach, a road to competitive high-Tc cables is proposed.Vital for large scale applications of high-T c superconductors [1,2] is the solution of the grain boundary problem, which manifests itself by the exponential decrease of the grain boundary critical current density J c of the high-T c cuprates as a function of the grain boundary angle [3,4].We propose to solve this problem using a threefold approach: through 1) grain alignment [3], 2) grain boundary doping [5], and 3) optimization of the microstructure to maximize the effective grain boundary area [6]. In contrast to the powder-in-tube technology where large grain boundary areas and grain alignment are used to enhance J c [7-9], today's coated conductor technologies [10][11][12] focus on grain alignment only. As we have shown, however, simple ways exist to also preferentially dope the grain boundaries [5] and engineer large effective grain boundary areas [13,14] to further enhance the performance of coated conductors.As pointed out in 1987, large effective grain boundary areas can be realized by engineering the microstructure of the superconductor to obtain grains with big aspect ratios, for example by stacking in a brickwall-type manner platelet-like grains on top of each other [6,7]. The enhancement of the critical currents hereby gained is responsible for the large J c of the Bi-based high-T c superconductors fabricated with the powder-in-tube technology [6-9]. Recently we found ways to use large effective grain boundary areas to enhance J c of coated conductors that consist of two-or three dimensional grain boundary networks, as illustrated in Fig. 1. Although it is clear that each one of the three techniques described substantially enhances J c , the increase that can be gained by utilizing all three, for example as shown by Fig. 2, is unknown.Therefore we have calculated the performance, which can be achieved by combining grain orientation, doping, and large effective grain boundary areas. Based on these calculations, optimized sets of parameters for the fabrication of coated conductors are derived. The calculation of current percolation through disordered networks of weak links, some of which may be Josephson junctions, is a complex problem [6]; and several algorithms have been developed for its solution (see, e. g. Ref. 6,(15)(16)(17)(18)(19). As the fast algorithms are limited to two-dimensional networks, for the present work a new one had to be devised. Like in several of the existing algorithms, to achieve the required speed, phase effects and self fields were neglected.
FIG. 2.Simplified sketch of a tape, fabricated by the rolling assisted biaxially textured substrate (RABiTS) technology, with a m...