2016
DOI: 10.1038/srep38816
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Coexistence of Write Once Read Many Memory and Memristor in blend of Poly(3,4-ethylenedioxythiophene): polystyrene sulfonate and Polyvinyl Alcohol

Abstract: In this work, the coexistence of Write Once Read Many Memory (WORM) and memristor can be achieved in a single device of Poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT: PSS) and Polyvinyl Alcohol (PVA) blend organic memory system. In memristor mode, the bistable resistance states of the device can be cycled for more than 1000 times. Once a large negative bias of −8V was applied to the device, it was switched to permanent high resistance state that cannot be restored back to lower resistance stat… Show more

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Cited by 20 publications
(5 citation statements)
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“…In this case, the graphene-doped PVA composite memristor resembles the trap-induced resistive switching modeling mechanism that has been widely discussed. The charge injected from the contacts is captured by the conductive dopant in a manner similar to the doping of PCBM or PEDOT:PSS in a PI or PVA matrix. , As shown in this work, significantly reproducible bipolar resistive switching behavior is observed when graphene is doped into a PVA matrix. This result implies that graphene, which has more edges or defects, acts as a carrier trapping site in the PVA–Gr composite film.…”
Section: Resultsmentioning
confidence: 99%
“…In this case, the graphene-doped PVA composite memristor resembles the trap-induced resistive switching modeling mechanism that has been widely discussed. The charge injected from the contacts is captured by the conductive dopant in a manner similar to the doping of PCBM or PEDOT:PSS in a PI or PVA matrix. , As shown in this work, significantly reproducible bipolar resistive switching behavior is observed when graphene is doped into a PVA matrix. This result implies that graphene, which has more edges or defects, acts as a carrier trapping site in the PVA–Gr composite film.…”
Section: Resultsmentioning
confidence: 99%
“…Recently, organic resistive switching memory devices (organic RRAM) have been studied extensively for future flexible and stretchable electronics [7]. In this class of materials, the switching mechanisms are attributed to metal migration from active electrodes [8,9], defect migration [10], charge transfers [11], charge trapping/de-trapping [12,13] and electrochemical/electro-active processes [14]. Many materials have shown WORM switching such as Organic-Inorganic perovskites [15], Graphene composites [16], Biomaterials [17], Quantum dots and composites [18].…”
Section: Introductionmentioning
confidence: 99%
“…These inorganic-semiconductor-based RRAMs exhibited remarkable memory characteristics with certain drawbacks due to the limitations of functional material including nonflexibility, nonrecyclability, and environmental unfriendliness. 128 Organic-semiconductor-based RRAMs have also been proposed to cope with the disadvantages of inorganic RRAMs such as poly(vinyl alcohol) (PVA), 49 poly(methyl methacrylate) (PMMA), 129 methylammonium lead iodide (CH 3 NH 3 PbI 3 ), 130 poly(3-hexylthiophene) (P3HT), 50 poly- (3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PE-DOT:PSS), 131 naphthalimide nanoparticles, 132 and so on, but they too have certain limitations such as a low conductivity and small lifetime. 133 Different classes of materials used as the functional layers of RRAMs are illustrated in Figure 1(a).…”
Section: Introductionmentioning
confidence: 99%