A theoretical study of the low-lying excited electronic states of thiocarbonyl chlorofluoride and their dissociation pathways Time-dependent quantum mechanical study of photodissociation of molecular oxygen in the Schumann-Runge continuumWe have theoretically studied the usefulness of ultrashort chirped laser pulses for laser control of photodissociation dynamics with a one-dimensional model system involving a potential well in the excited electronic state. The molecular system we treat in this paper entails three electronic states, a ground electronic state, and two excited electronic states. The ground electronic state is radiatively dipole-coupled with the lower of the two excited electronic states, while the two excited electronic states are themselves connected by diabatic coupling potential. Previously, we found a single linearly chirped ultrashort ͑in the order of fs͒ laser pulse can be employed to control photodissociation dynamics according to the sign of the chirp rate: A positively chirped pulse traps the molecule in the excited state potential well, while a negatively chirped pulse photodissociates the molecule rapidly. In the present paper we take into consideration the influence of the strength of the diabatic coupling and the reduced mass of the molecular system and show such a selectivity works best when the diabatic coupling is moderate and the molecular system is light. We explain these phenomena by a state selective excitation in vibrational states under the condition of adiabatic rapid passage ͑ARP͒ population transfer. We solve the integrodifferential equation of the molecular system involving the vibrational states explicitly, which is a quite different approach from that for the atomic case.