Cold plasma assisted deoxygenation of liquid phase glycerol at atmospheric pressure

Harris, Jonathan S.; Zhang, Kui; Phan, Anh N.

doi:10.1016/j.cej.2020.124698

Chemical Engineering Journal

2020

DOI: 10.1016/j.cej.2020.124698

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Cold plasma assisted deoxygenation of liquid phase glycerol at atmospheric pressure

Jonathan S. Harris

Kui Zhang

Anh N. Phan

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Cited by 13 publications

References 40 publications

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Application of nonthermal atmospheric‐pressure plasma irradiation as a new method for noncatalytic liquid‐phase selective oxidation of polyhydric alcohols

Chida,

Hiromori,

Shibasaki‐Kitakawa

et al. 2023

Plasma Processes & Polymers

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We have developed a new liquid‐phase noncatalytic selective oxidation of polyhydric alcohols such as glycerol. This method involves the use of a nonthermal atmospheric‐pressure plasma instead of precious‐metal catalysts. We found that noncatalytic selective oxidation of glycerol achieved a conversion comparable to that achieved by gold‐catalyzed oxidation, and the desired glyceric acid, which is a pharmaceutical raw material, was obtained. When the solution pH was changed from strongly alkaline to neutral, the main reaction switched from the one that occurs in the presence of gold catalysts to the one that occurs in the presence of platinum catalysts. These results suggest that the reactive oxygen species generated by nonthermal atmospheric‐pressure plasma irradiation vary depending on the solution pH.

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Application of nonthermal atmospheric‐pressure plasma irradiation as a new method for noncatalytic liquid‐phase selective oxidation of polyhydric alcohols

Chida,

Hiromori,

Shibasaki‐Kitakawa

et al. 2023

Plasma Processes & Polymers

View full text Add to dashboard Cite

show abstract

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Chemical Engineering Journal

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Cold plasma assisted deoxygenation of liquid phase glycerol at atmospheric pressure

Cited by 13 publications

References 40 publications

Application of nonthermal atmospheric‐pressure plasma irradiation as a new method for noncatalytic liquid‐phase selective oxidation of polyhydric alcohols

Application of nonthermal atmospheric‐pressure plasma irradiation as a new method for noncatalytic liquid‐phase selective oxidation of polyhydric alcohols

COx-free co-cracking of n-decane and CH4 to hydrogen and acetylene using pulsed spark plasma

One-step high-value conversion of heavy oil into H2, C2H2 and carbon nanomaterials by non-thermal plasma

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