We experimentally studied the characteristics of the collimated blue light (CBL) produced in 85 Rb vapor by two resonant laser fields exciting atoms into the 5D 3/2 state, using either the 5P 1/2 or the 5P 3/2 intermediate state. We compared the CBL output at different values of frequency detunings, powers, and polarizations of the pump lasers in these two cases, and confirmed the observed trends using a simple theoretical model. We also demonstrated that the addition of the repump laser, preventing the accumulation of atomic population in the uncoupled hyperfine ground state, resulted in nearly an order of magnitude increase in CBL power output. Overall, we found that the 5S 1/2 − 5P 1/2 − 5D 3/2 excitation pathway results in stronger CBL generation, as we detected up to 4.25 µW using two pumps of the same linear polarization. The optimum CBL output for the 5S 1/2 − 5P 3/2 − 5D 3/2 excitation pathway required the two pump lasers to have the same circular polarization, but resulted only in a maximum CBL power of 450 nW.